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filingDate 2007-09-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e0e32f950af6c52aadf42beca9e17c5d
publicationDate 2012-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2458040-C2
titleOfInvention Improved method of producing unsaturated carboxylic acid anhydrides
abstract FIELD: chemistry. n SUBSTANCE: invention relates to an improved method of producing unsaturated carboxylic anhydrides of general formula I, in which R is an unsaturated organic residue having 2-12 carbon atoms by re-anhydridising an aliphatic carboxylic anhydride through reaction with a carboxylic acid of general formula II, in which R is as defined above, in an apparatus consisting of a reaction region and a rectification column, wherein a) the reactants are fed into the reaction region in stoichiometric ratios, b) the carboxylic acid formed as a by-product is removed from the reaction mixture, c) the carboxylic anhydride of the formula I is subsequently distilled off, d) the unconverted reactants are recycled into the reaction region, e) the reaction region contains a heterogeneous catalyst and f) one or more polymerisation inhibitors are added. n EFFECT: improvement lies in that stoichiometric excess of one of the reactants is avoided, formation of secondary components is prevented and complete conversion of reactants is achieved. n 6 cl, 1 dwg, 2 ex
priorityDate 2006-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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