http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2440340-C2
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_ec5a60ce255cb641b0c16c33bd852230 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-18 |
| filingDate | 2008-11-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2012-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f0651e6fe64875d5756a4a4ba8516d9b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3319502ca44e0d04e0253b5991cbf4b7 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_38e51487ed6b68f27826173c0bf682ba http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_912accf1d62ea5ffa9defd73e9b7aeb4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_eed3cff0aab375f8b30a4c63a557da11 |
| publicationDate | 2012-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | RU-2440340-C2 |
| titleOfInvention | METHOD FOR COMBINED SYNTHESIS OF 1'-(3-1H-INDOLEMETHYL)-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2'3':1,9]CYCLOPROPANE AND 1'a-(3-1H-INDOLEMETHYL)1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE |
| abstract | FIELD: chemistry. n SUBSTANCE: invention relates to a method for combined synthesis of a novel 1'-(3-1H-indolemethyl)-1'-ethylformyl-(C 60 -1 h )[5,6]fullero[2',3':1,9]cyclopropane and 1'a-(3-1H-indolemethyl)-1'a-ethylformyl-1'a-carba-1'(2')a-homo(C 60 -1 h )[5,6]fullerene of general formula (1) and (2) : involving reaction of C 60 -fullerene with ethyl 2-(3-1H-indolemethyl)-2-diazoacetate in o-dichlorobenzene in the presence of a three-component catalyst {Pd(acac) 2 :2PPh 3 :4Et 3 Al}, taken in molar ratio C 60 :ethyl 2-(3-1H-indolemethyl)-2-diazoacetate:Pd(acac) 2 : PPh 3 : Et 3 Al=0.01:(0.01-0.10) : (0.0015-0.0025):(0.003-0.005):(0.006-0.01), preferably 0.01:0.05:0.002:0.004:0.008, at temperature 80°C for 0.5-1.5 hours. n EFFECT: improved method. n 1 tbl |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2598079-C1 |
| priorityDate | 2008-11-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 38.