http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2434838-C1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_cc7f805baf356e36b3a8954b3094b3fc |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-122 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-354 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J21-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C19-04 |
filingDate | 2010-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2011-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6fe0e772f7aa5cfdaa81ce231b418c3d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4d139fde98a0f0596d254040b192720c |
publicationDate | 2011-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | RU-2434838-C1 |
titleOfInvention | Method for co-synthesis of chloroalkanes and chloroform on solid catalyst |
abstract | FIELD: chemistry. ^ SUBSTANCE: invention relates to methods of converting chlorohydrocarbons, specifically to methods for simultaneous production of chloroform and chloroparaffins. Described is a method for co-synthesis of chloroform and chloroalkanes from tetrachloromethane and alkane, which is carried out in liquid phase in the presence of a solid catalyst which is a product of reacting copper chloride, 3-chloropropyl trimethoxy-siloxane, tertiary amine or derivatives of imidazole and silica gel. The tertiary amine used is compounds of general formula R1R2R3N, where R is methyl, ethyl, propyl or isopropyl. The imidazole derivative is methyl- or ethyl-imidazole. Content of copper in the catalyst is equal to 1.5-2 wt %. The process for co-synthesis of chloroform and chloroalkanes is carried out at temperature 160-190C and contact time of 3-5 hours in the presence of an organic additive selected from C2-C4 alcohols. ^ EFFECT: simplification of the process owing to exclusion of the step for purifying the end product from catalyst conversion products and resinous substances and possibility of using the catalyst many times. ^ 2 tbl, 14 ex |
priorityDate | 2010-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.