http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2434838-C1

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-122
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-354
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J21-08
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C19-04
filingDate 2010-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2011-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6fe0e772f7aa5cfdaa81ce231b418c3d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4d139fde98a0f0596d254040b192720c
publicationDate 2011-11-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2434838-C1
titleOfInvention Method for co-synthesis of chloroalkanes and chloroform on solid catalyst
abstract FIELD: chemistry. ^ SUBSTANCE: invention relates to methods of converting chlorohydrocarbons, specifically to methods for simultaneous production of chloroform and chloroparaffins. Described is a method for co-synthesis of chloroform and chloroalkanes from tetrachloromethane and alkane, which is carried out in liquid phase in the presence of a solid catalyst which is a product of reacting copper chloride, 3-chloropropyl trimethoxy-siloxane, tertiary amine or derivatives of imidazole and silica gel. The tertiary amine used is compounds of general formula R1R2R3N, where R is methyl, ethyl, propyl or isopropyl. The imidazole derivative is methyl- or ethyl-imidazole. Content of copper in the catalyst is equal to 1.5-2 wt %. The process for co-synthesis of chloroform and chloroalkanes is carried out at temperature 160-190C and contact time of 3-5 hours in the presence of an organic additive selected from C2-C4 alcohols. ^ EFFECT: simplification of the process owing to exclusion of the step for purifying the end product from catalyst conversion products and resinous substances and possibility of using the catalyst many times. ^ 2 tbl, 14 ex
priorityDate 2010-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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