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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C22B3-06
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C01F17-224
filingDate 2010-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2011-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f240e8aba823ecbc0deff2f969921fdd
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3412375fbc35d94711211e0ce61f81f0
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publicationDate 2011-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2430885-C1
titleOfInvention Method of extracting lanthanides from apatite concentrate
abstract FIELD: chemistry. n SUBSTANCE: apatite concentrate is decomposed with nitric acid to obtain nitrate-phosphate solution. Calcium nitrate and sodium fluosilicate are successively extracted from the solution. The solution is neutralised with ammonia to form a precipitate of phosphates of the main part of lanthanides and a mother solution with the residual part of lanthanides. The mother solution is treated by bringing it into contact with an amorphous titanium phosphate-based sorbent at pH of the solution equal to 1.4-1.7 with concentration of the residual part of lanthanides in the sorbent. The lanthanide-rich sorbent is separated, washed with water and treated with 0.5-3.0 M mineral acid with desorption of lanthanides. The amorphous sorbent used is one of the sorbents with the following composition: TiOHPO 4 ·nH 2 O, (Ti 1-x Zr x )OHPO 4 ·nH 2 O, TiONH 4 PO 4 ·nH 2 O, (Ti 1-x Zr x )ONH 4 PO 4 ·nH 2 O, where n≥1, x=0.05-0.5. n EFFECT: high degree of extraction of lanthanides from apatite concentrate. n 3 cl, 6 ex, 6 tbl
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