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filingDate 2010-03-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2011-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_32c9d0fba1976212bf4e53b0fe0b9622
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publicationDate 2011-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2428418-C1
titleOfInvention Method of producing n-nitromethyl azoles
abstract FIELD: chemistry. n SUBSTANCE: invention relates to organic chemistry and specifically to a method of producing N-nitromethyl azoles of formula n where R= , , , , , which can be used as biologically active substances and intermediates during synthesis of other azole derivatives. The method of producing N-nitromethyl azole derivatives is realised by treating a ketone with a corresponding azole acetic acid and nitric acid mixture at 50-60°C in the presence of 0.05-0.25 mole sodium nitrite per mole of the initial ketone. The volume ratio of nitric acid (58-70% concentration) to glacial acetic acid is equal to 1:6. n EFFECT: novel method of producing N-nitromethyl azole derivatives and synthesis of novel N-nitromethyl derivatives of 3-nitro-1,2,4-triazole. n 1 cl, 5 ex
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type http://data.epo.org/linked-data/def/patent/Publication

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