http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2356911-C1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9a4826ad2e87f9088cbefed19f2975f9 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-685 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-656 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-654 |
filingDate | 2007-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2009-05-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2d197aeb8bd09ae7ee14280cca732563 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8f216f37172cc14a711e117a4a1b25bd http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_49a6757b86d5a9fdf0ac2797149fadb6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9f1b6ff1c89420500b832ed9532ee024 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3a2effaba6961b07f077f8b70172dbba http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_541847087fac3d68ecc53b5ccfa43fad |
publicationDate | 2009-05-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | RU-2356911-C1 |
titleOfInvention | Method of obtaining polyethylene and copolymers of ethylene with alpha-olefins with wide molecular mass distribution |
abstract | FIELD: chemistry. n SUBSTANCE: present invention relates to the method of obtaining polyethylene and copolymers of ethylene with alpha-olefins with a wide range of molecular mass distribution, using Ziegler type supported catalyst, containing a compound of a transition metal on a magnesium containing carrier. The process is carried out in the presence of a catalyst which contains a vanadium compound (VCl 4 , VOCI 3 , V(OR) x Cl 3 - x ) on a magnesium containing carrier, which is obtained from reacting a solution of organomagnesium compound with the formula: Mg(C 6 H 5 ) 2 n MgCl 2 mR 2 O, where: n=0.37-0.7, m=2, R 2 O is ether with R=i-Am, n-Bu, with a product of reacting alkylchlorosilane with the formula: R' k SiCl 4-k , where R is alkyl or phenyl, k=0, 1, 2, and silicon tetraalkoxide Si(OEt) 4 . Dialkylaromatic ether D is used in the organomagnesium compound MOC. Polyethylene and copolymers of ethylene and alpha-olefins with wide molecular-mass distribution are obtained using the above described catalyst in conjunction with organoaluminum co-catalyst at 50-100°C in a medium of hydrocarbon diluent. Hydrogen, taken in amount of 5-50 vol.%, is used as the regulator of molecular mass of the polymer. n EFFECT: during polymerisation of ethylene on this catalyst, polyethylene is produced with high packed density and narrow particle size distribution, as well as wide molecular mass distribution. n 3 cl, 5 ex, 1 tbl |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2570645-C1 |
priorityDate | 2007-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 65.