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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J37-04
filingDate 2003-12-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2006-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d5fb2337a85f19c49c87707dfb55dec2
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publicationDate 2006-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2267497-C2
titleOfInvention Method for preparing catalyst for polymerization of butadiene and copolymerization of butadiene with coupled dienes
abstract FIELD: chemistry of polymers, chemical technology, catalysts. n SUBSTANCE: invention relates to a method for preparing a catalyst used in polymerization of butadiene and copolymerization of butadiene with coupled dines. Method involves interaction of components comprising the compound of rare-earth element, diisobutyl aluminum hydride, triisobutyl aluminum, alkyl aluminum halide and coupled diene. Firstly, method involves mixing rare-earth element and coupled diene solutions with diisobutyl aluminum hydride solution, and the mixture is kept for 10-30 min at stirring, and then triisobutyl aluminum and alkyl aluminum halide solutions are added. After mixing all components the mixture is kept for 10-15 h in the following mole ratio of components: rare-earth element : diisobutyl aluminum hydride : triisobutyl aluminum : alkyl aluminum halide : coupled diene = 1:(3-12):(6-12):(1.5-3):(2-20), respectively, wherein rare-earth element carboxylate or alcoholate is used as a source of rare-earth element. Invention provides preparing the high-effective catalyst allowing preparing highly stereoregular polybutadiene and butadiene copolymer with the couples diene with simultaneous reducing the range of molecular-mass disposition by 3-3.5 times. n EFFECT: improved preparing method. n 5 ex
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2570019-C9
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priorityDate 2003-12-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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