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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N27-48
filingDate 1996-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1998-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3046906b6f827698bd5b0a6d924f3618
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publicationDate 1998-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2102736-C1
titleOfInvention Method of inversion-volt-amperometric determination of heterovalent arsenic forms in aqueous solutions
abstract FIELD: analytical chemistry. SUBSTANCE: method is based on electroaccumulation of As (III) on stationary mercury electrode in the presence of ions Cu 2+ followed by recording curve of cathode reduction of concentrated copper arsenide. Method involves determination of As (III) content at background of 0.6 M HCl + 0.04 M N 2 H 4 HCl + 50 mg/l Cu 2+ by height of inversion cathode peak at potential (-0.72) V, chemical reduction of As (V) to As (III), measurement of total water-soluble content of arsenic and determination of As (V) content by concentration difference of total and trivalent arsenic. Method involves additional addition of HCl, KJ and Cu 2+ to solution where As (III) content has been determined, Chemical reduction of As (V) to As (III) is carried out in background electrolyte which has the following components: 5.5 M HCl + 0.1 M KJ + 0.02 M N 2 H 4 2 HCl + 100 mg/l Cu 2+ . Electroaccumulation of arsenic is carried out at potential (-0.55 ± 0.01) V, cathode volt-ampere curve is recorded at the range of voltage from (-0.55) V to (-1.0) V and total arsenic content in solution is determined by height of inversion peak at potential (-0.76 ± 0.01) V. EFFECT: improved method of determination. 8 dwg
priorityDate 1996-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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