http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2014102353-A
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-363 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C53-21 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-363 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C255-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C255-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-307 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-62 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-64 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-307 |
| filingDate | 2012-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2015-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | RU-2014102353-A |
| titleOfInvention | Fluorination of esters of acrylic acid and their derivatives |
| abstract | 1. The method of fluorination of a double bond, which includes: the formation of a reaction mixture containing a fluorocarbon solvent, fluoride gas and a compound of formula 1 where R is hydroxy, alkoxy, chlorine or —OC (O) CH = CH, with the formation of a compound of formula 2 with a yield of at least at least 50%, where R is hydroxy, alkoxy, chloro, —OC (O) CHFCHF. 2. The method according to claim 1, wherein R is methoxy. The method according to claim 1, wherein R is hydroxy. The method according to claim 1, wherein R is chlorine. A method according to any one of claims 1 to 4, characterized in that R is methoxy. A process for fluorinating a double bond, which comprises: forming a reaction mixture containing a fluorocarbon solvent, fluoride gas and a compound of formula 5 to form a compound of formula 6.7. A method according to any one of claims 1, 2, 3, 4 or 6, characterized in that the fluorocarbon solvent has a melting point of less than about -20 ° C. A method according to any one of claims 1, 2, 3, 4 or 6, characterized in that the reaction mixture is a liquid at a temperature of less than about -40 ° C. A method according to any one of claims 1, 2, 3, 4 or 6, characterized in that the fluorocarbon solvent has a boiling point of more than about 30 ° C. 10. A method according to any one of claims 1, 2, 3, 4, or 6, characterized in that the fluorocarbon solvent is 2H, 3H-decafluoropentane, eicosafluorononane, tetradecafluorohexane, tetradecafluoro-2-methylpentane, hexafluorobenzene, octadecafluorofluorotentole fluoride fluoride octane , perfluoro (1,3-dimethylcyclohexane), perf�� |
| priorityDate | 2011-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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