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filingDate 2008-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2010-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2008140122-A
titleOfInvention METHOD FOR PRODUCING ETHylene AND α-OLEFIN COPOLIMERS
abstract 1. A method for producing ethylene copolymers having at least a bimodal branching distribution of side chains, comprising copolymerizing ethylene with α-olefins in the presence of a catalyst system comprising the following components:! A) at least one monocyclopentadienyl complex comprising a structural fragment of the formula (Cp-Z-A) Cr (I), in which! Cp-Z-A means a ligand of formula (II)! ! where R1A-R4A independently of each other mean hydrogen, alkyl with 1-20 carbon atoms, alkenyl with 2-20 carbon atoms, aryl with 6-20 carbon atoms, alkylaryl containing from 1 to 10 carbon atoms in the alkyl fragment and 6- 20 carbon atoms in the aryl fragment, NR11A 2, N (SiR11A 3) 2, OR11A, OSiR11A 3, SiR11A 3, BR11A 2, where organic radicals R1A-R4A can be substituted with halogens and where at least two of the vicinal radicals R1A -R4A are linked to form a five- or six-membered ring, and / or two vicinal radicals R1A-R4A are linked to form a heterocycle containing at least one atom selected from the group consisting of nitrogen (N), phosphorus (P), oxygen (Oh) and sulfur (S),! Z means a bridge between A and Cp, which has the formula! ! where L stands for carbon or silicon,! R5A, R6A mean hydrogen, alkyl with 1-20 carbon atoms, alkenyl with 2-20 carbon atoms, aryl with 6-20 carbon atoms, alkylaryl containing from 1 to 10 carbon atoms in the alkyl fragment and 6-20 carbon atoms in the aryl fragment, or SiR11A 3, where organic radicals R5A and R6A can be substituted with halogens and R5A and R6A can also be connected to form a five- or six-membered ring,! And means a group! ! where E1A-E4A stands for carbon or 1-2 nitrogen atoms,! R7A-R10A independently of each other mean hydrogen
priorityDate 2002-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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