http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2008129561-A
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-00 |
| filingDate | 2008-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2010-01-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | RU-2008129561-A |
| titleOfInvention | METHOD FOR COLLECTING 1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANE AND 1'a-ETHYLFORMIL-1'a-CARBA-1 '(2') a-HOMO (C60-Ih) [5,6] FULLERENA |
| abstract | The method of co-production of 1′-ethylformyl- (C60-Ih) [5,6] fullero [2 ′, 3 ′: 1,9] cyclopropane and 1′a-ethylformyl-1′a-carba-1 ′ (2 ′) a-homo (C60-Ih) [5,6] fullerene of the general formulas (1) and (2)! ! the interaction of C60-fullerene with diazoacetic ester (N2CHCOOEt), characterized in that the reaction is carried out in o-dichlorobenzene (o-DCB) in the presence of a three-component catalyst {Pd (acac) 2: 2PPh3: 4Et3Al}, taken in a molar ratio of C60: diazo : Pd (acac) 2: PPh3: Et3Al = 0.01: (0.03-0.07) :( 0.0005-0.0015) :( 0.001-0.003) :( 0.002-0.006), preferably 0.01: 0.05: 0.001: 0.002: 0.004, at temperature 80 ° C for 0.5-1.5 hours |
| priorityDate | 2008-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 27.