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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C13-40
filingDate 1991-02-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1993-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4a631ab2d5f9fd5b0baa237687eec5c6
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publicationDate 1993-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-1796606-C
titleOfInvention 2-methylene-3-exo-vinyl-5(6)-ethylidene norbornane as copolymer for preparing thermostable and thermoplastic polymeric ethylene and propylene-base materials and process for preparing thereof
abstract Usage: as a monomer for the production of thermostable and thermoplastic polymeric materials based on ethylene and propylene. SUMMARY OF THE INVENTION: 2-methylene-3-exosinyl-5 (6) -ethylidene-norbornane product, 68% yield, bp. 81-82 ° C (22 mmHg). The compound is prepared by reacting 5-ethylidene-norbornene-2 with allyl acetate in benzene, or toluene, or xylene, or heptane, or hexane in an inert gas atmosphere at 50-80 ° C in the presence of a catalytic system including bis- (if - allyl) nickel and triisopropylphosphite at a molar ratio of 1: (4-8), wherein the molar ratio of 5-ethylidene-norbornene-2 to allyl acetate is 1: (0.8-1.5). The reaction is carried out in the presence of zeolites with a pore diameter of 4-5 A. 2 tab. (L C
priorityDate 1991-02-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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