abstract |
A method of producing hydrocarbons by thermophtholysis of polyolefins under the influence of radiation having a wavelength spectrum of 250-2600 nm, at 200-250 ° C in the presence of a catalyst containing oxides of molybdenum (VI), silicon, magnesium, sulfur (VI), aluminum, nickel (II) or cobalt (II), zeolite I-mordenite with silicate module 10, zeolite H - LSM-8 with silicate module 30, in the following ratio of components in the catalyst, wt.%: Nickel (II) or cobalt (II) oxide 6.5-10.0; molybdenum (VI) oxide 0.5-20.0, silicon oxide 1.0-10.0, magnesium oxide 0.5-5.0, sulfur dioxide (VI) 0.1-2.0, zeolite N-mordenite with a silicate module 10 5.0-60.0, zeolite H - LSM 8 with a silicate module 30-2.0-30.0, alumina up to 100. The used catalyst has the above composition. 2 s.p. crystals, 5 tab. Ј |