http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RO-86593-B1

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-36
filingDate 1983-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6fba02dd139fd279e8cbf9ec6572160f
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publicationDate 1985-05-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RO-86593-B1
titleOfInvention PIRIDINIUM CUTTING WATER AND PROCESS FOR PREPARING THEM
abstract The invention relates to quaternary pyridine salts which exhibit a corrosion inhibiting effect in a 15% HCL medium at concentrations of 100 ... 500 ppm, as well as bacteriostatic effects, having the general formula I wherein M is 2 N is 1 ... 2, R is C 2 to C 12 alkyl, X is chloro, bromo, iodo, water-soluble surfactants having a refractive index ranging from nD to 20 = 1, 4785 ... 1.5250 and melting points in the case of the crystalline solids between 56 DEG-137 DEG C. The process for preparing the quaternary salts consists in quaternizing pyridine with alkyl (R) phenoethoxylate with 2-35 moles of ethylene oxide in the presence of an alcohol selected from ethyl alcohol obtained by the etherified alkyl ethoxylate reaction with a lower aliphatic halogen acid selected from monochloroacetic acid, monobromoacetic acid, monochloropropionic acid, monobromopropionic acid in the presence of catalysts specific (ion exchange cations, p-toluenesulfonic acid, phosphoric acid, about 1% phosphoric acid) at a temperature of 80-85 ° C, in the presence of benzene which favors the removal of the reaction water in the form of azeotrope for 2 ... 6 hours, the quaternization reaction, in the presence of an alcohol selected from ethyl isopropyl alcohol, in an inert gas preferably nitrogen gas, at temperatures of from 85 to 145 ° C and pressures of 1 ... 5 ° for 6 ... 20 hours.
priorityDate 1983-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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