http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RO-83831-B1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_bc49810f79865ea7e05a8d033d2c1e2a |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L25-04 |
filingDate | 1982-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c6486dbd027e8ec582ab6681db3f3865 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_024211a789ffb6b251f0fa4e0244e4a3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_eb5a8308e170ee72d97c2146ef1d0d71 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_59245d8d21109eefddc88fd669f93051 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d117dbf75aae3bf6ecb87193d2ef391f |
publicationDate | 1984-04-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | RO-83831-B1 |
titleOfInvention | PROCESS FOR OBTAINING ACRYLIC TREATMENTS |
abstract | The invention relates to a process for obtaining acrylic resins for the manufacture of paints and adhesives applied on mineral supports which, in order to ensure storage stability, physico-mechanical characteristics and improved weathering, are copolymerised with a (meth) acrylic ester selected from methyl, ethyl, butyl, isobutyl, hexyl and 2-ethylhexyl (meth) acrylate or mixtures thereof with 96: 4 to 70: 30 wt.% glycidyl methacrylate, in the presence of toluene, a peroxide initiator selected from 0.5 ... 4% tert -butyl peroxide and 0.1 to 5% by weight of the tert-butyl mercaptan chain regulator relative to the total monomers at a temperature of refluxing the solvent to a final conversion of at least 98%, the resulting copolymer being further reacted with 2 to 20% by weight of acrylic acid based on the total monomer in the presence of a hydroquinone as an inhibitor, in the proportion of 100-1000 ppm based on the unsaturated acid, and a basic catalyst for the opening of the amine, phosphine or aromatic tertiary amine oxirane ring in the proportion of 0.2-2% relative to glycidyl acrylate at the reflux temperature of the solvent until an acidity index of at most 5 mg KOH / g is reached, after which the solvent is removed by vacuum distillation, replaced with a mixture of (meth) acrylic esters and hydrocarbon monomers , for example styrene and vinyl-toluene, and the resin so obtained is pre-accelerated with 0.5-5% of a mixture of polysulfide polymers and tertiary amines in a ratio of 100 to 1 to |
priorityDate | 1982-02-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 41.