http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RO-135066-A2

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-76
filingDate 2019-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2021-06-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RO-135066-A2
titleOfInvention POLYESTERS WITH POLYESTER-AMIDIC STRUCTURE CONTAINING MESOGENIC STRUCTURAL UNITS FOR SEMI-FLEXIBLE POLYURETHANE FOAMS AND METHOD OF OBTAINING THEM
abstract The invention relates to a process for obtaining polyols with a polyester-amide structure containing mesogenic structural units for semiflexible polyurethane foams. The process according to the invention consists in the successive steps of: (1) PET glycolysis in the presence of a mixture of diethylene glycol and polyethylene glycol 600, in a molar ratio of 50 ... 100/0 ... 50, in a molar ratio of PET / glycols of 1 /3..4.5, in the presence of 5% molar relative to PET catalyst 1,8-Diazabicyl [5.4.0] undec-7-ene at 190 ° C, under stirring, nitrogen atmosphere and total reflux , for 3-4 hours, (2) aminolysis with an aromatic diamine in the presence of 5% molar to PET, 1,5,7-Triazabicyl [4.4.0] dec-5-ene catalyst, under the same conditions , for 5 h, (3) esterification of the reaction mixture with adipic acid, in molar ratio to PET of 1.5-2, in the presence of titanium tetraisopropoxide catalyst, at a temperature of 200-205 ° C , for 4 ... 6 h, resulting in polyols with an average molecular weight of 630 ... 2000 g / mol, acidity index of 1.5 ... 3.5 mg KOH / g, hydroxyl index 50 ... 180 mg KOH / g, functionality 2 and dynamic viscosity at 25 ° C of 7000-15000 cP.
priorityDate 2019-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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