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publicationDate 2019-01-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RO-133049-A2
titleOfInvention OLIGOESTER-POLYOLES OF POLYETHYLENEFTALATE WASTE AND RENEWABLE MATERIALS, THE PROCESS FOR THEIR OBTAINING AND COMPOSITION FOR STRAW POLYURETHANE FOAM, CONTAINING OLIGOESTERS-POLYOLES RESULTS
abstract The invention relates to oligo-polyols, a process for making and a composition thereof based on polyurethane foams. The oligoester polyols according to the invention are composed of 25 ... 27% of structural units of aromatic carboxylic acids, 8-10% of aliphatic dicarboxylic acid units of 4 ... 6 carbon atoms, 63 ... 68% of units structural aliphatic diols or linear or branched oxyalkylenediols with 2-6 carbon atoms, 6-7% aliphatic oxyalkylene polyol units with 4 ... 6 primary hydroxyl functions and 8 ... 12% gravimetric vegetable oil. The process according to the invention consists in the degradative transesterification of PET waste in the presence of a mixture of diols and vegetable oil as well as an organic catalyst at a maximum temperature of 180 ° C followed by esterification of the products with mixtures of aromatic and dicarboxylic acids aliphatic at 205 ° C and atmospheric pressure. The composition according to the invention contains 20 ... 55% oligoester polyols, as well as common processing ingredients.
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