http://rdf.ncbi.nlm.nih.gov/pubchem/patent/PL-403012-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_6a40d3b31ee79490d722dd11f5e0c77a http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_7339501040a829287a6ee236092a9e00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-85 |
filingDate | 2013-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1772564ee5ea452e78fb9b2be057a52e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2428ac2267b8857acd76e45d4347e776 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_229625c20f0cd5fe6caab0c9acf9d0ae http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_778fa30e1365195fdf72f8a11a4c08c1 |
publicationDate | 2014-09-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | PL-403012-A1 |
titleOfInvention | Method for obtaining α, ω-dihydroxy polycaprolactone derivatives |
abstract | Method for the preparation of α, β-dihydroxy polycaprolactone derivatives of the general formula H- [Ax] -ORO- [By] -H, in which A and B are the group -O- (CH2) 5-CO, R is an alkyl of at least two atoms C, x, y are natural numbers of x? 1, y? 0, in the polymerization reaction of β-caprolactone in an organic solvent or without a solvent, in the presence of an initiator, the polymerization reaction is carried out in the presence of titanium (IV) complexes as polymerization initiators with the general formula [Z2 (L) Ti] 2 ( ORO), in which the L ligand is a cyclopentadienyl or pentamethylcyclopentadienyl group, Z is F, Cl, Br, J, and R is as defined above, at a temperature from 100 ° C to 160 ° C, with a molar ratio of Ti to monomers from 1:10 to 1: 1000. Obtained α, β-dihydroxy polycaprolactone derivatives are used in the synthesis of many polymers as a polyol component, e.g. in the synthesis of polyurethanes, improving, among others their biodegradation. |
priorityDate | 2013-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 20.