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publicationDate 2002-03-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber NZ-508191-A
titleOfInvention A method of modulating surface sizing properties such as porosity reduction, resistance to liquid penetration and surface strength when used as surface size on paper
abstract Degraded, hydrated particulate starches that are hydrophobically modified and a method of providing paper with reduced porosity comprising applying to the surface of a paper substrate an effective amount of a surface sizing composition which comprises such starch. In particular, the starches are those in which the starch base is degraded to a water fluidity (WF) of from about 10 to 80 or the modified and/or particulate starch is degraded using a substantially equivalent amount of degradation agent and substantially the same reaction conditions. The starch is modified with a hydrophobic hydrocarbon group of 5 to 23 carbon atoms at about 1 to 20% substitution level by weight of bound hydrophobe based on the weight of starch, and the hydrated starch has a volume average hydrated particle size of at least 20 microns and a volume fraction of hydrated particles at 1% solids of at least 5 %.
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