http://rdf.ncbi.nlm.nih.gov/pubchem/patent/NL-289638-A
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-18 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-33 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-33 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-52 |
publicationNumber | NL-289638-A |
abstract | In the liquid phase oxidation of C4- 8 saturated hydrocarbons to alcohols and ketones with a molecular oxygen containing gas in presence of boric acid or a dehydrated form thereof at 140-180 DEG C., the partial pressure of water in p.s.i. over the reaction mixture at T DEG C is more than P but not more than P1 given by the equations log10P1 = 0.0107T + 0.068 log10P = 0.0175T - 1.85 The intermediate boric acid esters may be isolated, but are usually directly hydrolysed to the desired alcohol, e.g. by heating with water. The end product contains ketone as by-product. Specified starting materials are cyclopentane, cyclohexane, cycloheptane, cyclooctane, mono and dimethylcyclohexanes, n-pentane, n-hexane, n-heptane and the methylpentanes. |
priorityDate | 1962-06-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 35.