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filingDate 2015-11-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_05dd319bcc9f99ea00a8512d1324a5d6
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publicationDate 2020-08-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber MY-176950-A
titleOfInvention Separating method for polyol mixtures with close boiling points
abstract This invention discloses an approach for the separation of the close-boiling mixture of polyols. The raw material is ethylene glycol (13) containing miscellaneous polyols (such as 1,2-propyleneglycol and 1, 2-butanediol) (12). Over an acid catalyst, these miscellaneous polyols (12), through (1) a dehydration reaction, (2) pinacol rearrangement , and (3) acetalization or kietalization reaction, are converted into aldehydes (small amounts), acetals, and ketals (trace amount) , which are simultaneously and readily separated via distillation. Meanwhile, after the reaction, the mixture is further separated to obtain an ethylene glycol (13) product at a high purity. The invention provides a technique to remove the miscellaneous polyols (12) from ethylene glycol (13) via liquid-phase dehydration reactions under mild conditions, with low energy consumption. lln particular, this approach is markedly effective for the removal of 1,2-butanediol that is difficult to be removed via conventional techniques. The purity of the resulting ethylene glycol (13) product is high, and value-added acetals or ketals are co-produced. In addition , a certain amount of acetaldehyde (22), propanal 23), acetone (24), etc., can also be produced as raw chemical materials. This invention is a green and environmentally sound technique to convert the crude ethyl,ene glycol (13) product that is generally difficult to be separated into high-purity ethylene glycol (13) and other chemical products.
priorityDate 2014-11-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 44.