http://rdf.ncbi.nlm.nih.gov/pubchem/patent/MX-2011005827-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_8e0bf0928b608797b70bbc2b91c7e52e |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D401-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-80 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D213-803 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-80 |
filingDate | 2009-12-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c206d232609bdbc659643d2ba9a554d6 |
publicationDate | 2011-06-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | MX-2011005827-A |
titleOfInvention | PROCESS FOR MANUFACTURING DERIVATIVES OF ACID 5-METOXIMETHYLPIRIDIN-2,3- DICARBOXYLICS SUBSTITUTED. |
abstract | Process for the manufacture of derivatives of 5-methoxymethylpyridine-2,3-djcarboxylic acid. Abstract. A process for the manufacture of a 2,3-disubstituted-5-methoxymethylpyrine of the formula (I), where Z is H or halogen; Z1 is H, halogen, CN or NO2; Y2 is OM, and M is an alkali metal or an alkaline earth metal, comprising the step of: (i) reacting a compound of the formula (II) where Q is an aliphatic or cyclic, saturated, partially unsaturated or aromatic tertiary amine ; Z is H or halogen; Z1 is H, halogen, CN or NO2; Y1 and Y2 each are independently OR1, NR1R2, or when taken together Y1 Y2 is -0-, -S- or -NR3-; R1 and R2 each are independently H, C1-C4 alkyl optionally substituted with C1-C4 alkoxy or phenyl optionally substituted with one to three C1-C4 alkyl groups, C1-C4 alkoxy groups or halogen atoms, or phenyl optionally substituted with one to three C1-C4 alkyl groups, C1-C4 alkoxy groups or halogen atoms; R3 is H or C1-C4 alkyl in a methanol / mixture H20, which comprises at least 20% by weight H20 (based on the sum of water and bromine (II), with a base comprising MOCH3 and / or MOH, where M is alkali metal or alkaline earth metal, under pressure in a closed container at a temperature of from 75 to 110 ° C. The compounds of the formula (I) are useful intermediates in the synthesis of herbicidal imidazolinones, similar to imazamox. |
priorityDate | 2008-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 79.