http://rdf.ncbi.nlm.nih.gov/pubchem/patent/MX-166891-B

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filingDate 1987-07-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ed9eb0bfff70c098606e14d675a738e4
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5e55585a9f735beedcf15834716635eb
publicationDate 1993-02-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber MX-166891-B
titleOfInvention HYDROFORMULATION USING LOW VOLATILITY / ORGANIC SOLUBLE PHOSPHINE COORDINATING GROUPS
abstract The present invention relates to a nonaqueous hydroformylation process for producing aldehydes, consisting of: reacting an olefinically unsaturated organic compound with carbon monoxide and hydrogen, in a nonaqueous hydroformylation reaction medium containing a complex catalyst of a solubilized organic Group VIII phosphor and transition metal coordinating group and a free phosphor coordinating group, where the hydroformylation reaction conditions comprise a reaction temperature of from about 45 to about 200 degrees C, a total gas pressure of hydrogen, carbon monoxide and olefinically unsaturated compound of less than about 105.45 kilograms per absolute square centimeter; wherein the H2: CO molar ratio of gaseous hydrogen or carbon monoxide is within the range of approximately 1:10 to 100: 1; and wherein the reaction medium contains at least about 4 moles of the total free phosphorous coordinating group per mole of the Group VIII transition metal in the medium; characterized in that it comprises: employing as the phosphor coordinating group of the complex catalyst and as the coordinating group of free phosphorus, a monosulfonated tertiary phosphine salt.
priorityDate 1986-07-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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