http://rdf.ncbi.nlm.nih.gov/pubchem/patent/LU-58495-A1
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2325-18 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J5-2243 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08L25-18 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L25-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08J5-22 |
| filingDate | 1969-04-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1969-11-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | LU-58495-A1 |
| abstract | 1,220,776. Cation exchange membranes. RHONE - POULENC S.A. 29 April, 1969 [29 April, 1968], No. 21897/69. Heading C3P. [Also in Division B1] A cation exchange membrane made of a homogeneous mixture of (a) a poly-p-vinylphenol, which is optionally halogenated, and which is cross-linked via the oxygen atoms of its hydroxyl groups and substituted by cation exchange radicals, and (b) an inert polymer may be prepared by forming a layer of a solution in and organic solvent of the inert polymer and the poly-p-vinylphenol and then, either successively or simultaneously, evaporating the solvent, cross-linking the poly-p-vinylphenol by reaction with its hydroxyl groups and introducing the cation exchange radicals. The inert polymer is one which does not interfere with the cross-linking of the poly-p-vinylphenol or the introducton of cation-exchange radicals and in particular is inert to halogenated compounds and sultones. Suitable polymers are polyvinyl chloride and a copolymer of vinyl chloride with vinylidene chloride or vinyl acetate. Cross-linking may be effected by dehydration in an inert medium containing hexamethylphosphotriamide or dioxane or by treatment of the salt of the polymer with a compound containing at least two reactive halogen atoms e.g. o- or p-xylylene dihalide or 3,3 - bis(halogeno - methyl) - oxetane. Crosslinking and radical introduction may be effected by reaction with a polysultone e.g. spirobi-2: 2<SP>1</SP>- propanesultone. Exchange radicals may be introduced by sulphonation with e.g. sulphuric acid, oleum, chlorosulphonic acid or a monosultone e.g. propanesultone. The membrane may also contain a quaternary ammonium salt and a hexaalkyl phosphotriamide. In the examples are also used poly(4 - hydroxy - 3 - chlorostyrene), poly(4 - hydroxy - 3 - bromostyrene), methyltrilaurylammonium chloride and tributyl orthophosphate. |
| priorityDate | 1968-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 39.