http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-960014109-A

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filingDate 1995-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1996-05-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-960014109-A
titleOfInvention 2-hvdroxyphenyltriazine, a process for their preparation and their use as an ultraviolet absorber in organic materials
abstract The present invention relates to 2-hydroxyphenyltriazines of the general formula (I) and homopolymers and copolymers obtainable therefrom and their preparation. :n n n n n n n n Wherein E 1 and E 2 are, independently of each other, a group of the general formula (Ia) or (1b)n n n n n n n n Wherein, A is -C (= O) -CR 5 = CH-R 6 , and; R 1 isn n n n n n n n -CH 2 -C (= CH 2) -R 10, - (CH 2) P -SiR 11 R 11 '-CH = CH 2 -C (= O) - (CH 2) q -CH 2 or -C ( = O) -O-CH 2 -C (= CH 2) -R 10 , and; And when R 3 'is -O-CR 8 R 8 ' - (CH 2 ) 1 -XA, R 1 is additionally C 1 -C 18 alkyl or may be replaced by -O-, -CO- Or the number of C 3 -C 20 alkyls including D is -O-CO-; Or E 1 is a group of the general formula (Ia) in which the radicals R 1 and R 14 are not both hydrogen and R 1 is in addition a group -A-CH 2 -CH (XA) -CH 2 -OR 7 , -CR 8 r 8 '- (CH 2) 1 -XA, -CH 2 -CH (OA) -R 9, -CH 2 -CH (OH) -CH 2 -XA, -CHR 8 - (CH 2) r -C ( = O) -O-CH 2 -CH (OH) -CH (OH) -CH 2 -OZ and -CR 8 R 8 '- (CH 2 ) 1 -C (= O) -XA; And when E 1 is a group of general formula (Ib), R 1 can additionally be -CH 2 -CH (XA) -CH 2 -OR 7 ; R 2 'are independently of each other C 1 -C 12 alkyl, cyclohexyl, C 3 -C 6 alkenyl, halogen, phenyl or trifluoromethyl; R 2 'are independently of each other C 1 -C 18 alkoxy, C 3 -C 18 alkenoxy and -OHeH is -O-CO-R 2 ; R 3 and R 3 'independently of one another are H 1 -O-CH 2 -CH (XA) -CH 2 -OR 7 ,n n n n n n n n -O-CH 2 -C (= CH 2) -R 10, -O- (CH 2) P -SiR 11 R 11 '-CH = CH 2, -OC (= O) - (CH 2) q -CH 2, or -OC (= O) -O-CH 2 -C (= CH 2) -R 10, -O-CR 8 R 8 '- (CH 2) 1 -XA, -O-CH 2 -CH (OA ) -R 9, -O-CH 2 -CH (OH) -CH 2 -XA, -O-CHR 8 - (CH 2) 1 -C (= O) -O-CH 2 -CH (OH) -CH 2- OA, -CR 8 R 8 - (CH 2 ) 1 -C (═O) -XA, C 1 -C 18 alkyl, C 6 -C 12 cycloalkyl, C 3 -C 18 alkenyl, OR 131 , halogen, trifluoromethyl, phenyl, phenyl-C 1 -C 4 alkyl, -CH 2 , C 1 -C 18 alkyl-S (= O) t -; R 4, R 4 'and R 4 "are independently H, C 1 -C 18 alkyl and each C 3 -C 6 alkenyl, -OR 131, methyl, halogen, trifluoromethyl, phenyl, phenyl -C 1 -C 4-alkyl, mono-to tri -C 1 -C 4 alkyl substituted phenyl, -C 1 -C 4 alkyl, -CN, -C 1 -C 18 alkyl, -S (= O) t - or phenyl, -S ((= O) t -; R 5 is H, CH 2 -COOR 13 , C 1 -C 4 alkyl or -CN; R 6 is H, CH 2 -COOR 13 , C 1 -C 4 alkyl or -CN; R is selected from the group consisting of H, -COOR 13 , C 1 -C 4 alkyl or phenyl, R 7 is C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 3 -C 18 alkenyl, phenyl, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 3 -C 8 alkenoxy, halogen or a fluoromethyl radical, phenyl-C 1 -C 4 alkyl, one or more -O- C 3 -C 50 alkyl comprising; 1-adamantyl; 2-adamantyl; norbornyl, 2-Mesnil Torr bornyl or one to three C 1 -C 4 alkyl, C 3 -C 8 alkene Oxy, C 1 -C 8 alkoxy, halogen or CR 3 radicals R 9 is C 1 -C 4 alkyl, phenyl or phenyl-C 1 -C 4 alkyl, R 10 is H or -second 3 , R 11 and R 11 'are independently of each other C 1 -C 4 alkyl or phenyl or phenyl substituted by one to three C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 3 -C 8 alkenoxy, halogen or a fluoromethyl radical, R 12 is H , C 1 -C 18 alkyl, C 2 -C 18 alkenyl, phenyl, phenyl-C 1 -C 4 alkyl, C 5 -C 12 cycloalkyl, C 1 -C 12 alkoxy, phenoxynorborn- N is 1, 1, 5-norbornene-2-yl or 1-adamantyl, R 13 is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, phenyl, C 5 -C 12 cycloalkyl, C 3 -C 50 alkyl or more -O-, one to three C 1 -C 8 containing alkoxy, C 3 -C 8 alkene, aryloxy, substituted by a methyl radical or a halogen-free fluoro-phenyl, phenyl -C 1 -C 4 alkyl, 1-adamantyl, 2-adamantyl, norbornyl or 2-norbornyl, and; R 14 and R 15 are independent to each other, H, C 1 -C 18 alkyl, C 3 -C 18 alkenyl, C 6 alkyl, halogen, -C 12 seek OF 3, phenyl, phenyl -C 1 -C 4 Alkyl, CN, C 1 -C 18 alkyl-S (= O) t -, phenyl-S (= O) t -OR 131 ; R 131 is selected from the group consisting of C 1 -C 18 alkyl, C 3 -C 18 alkenyl, OH, C 1 -C 18 alkoxy, C 5 -C 12 cycloalkoxy, C 3 -C 6 alkenoxy, halogen, COOR 13 , 2 , -COHNR 132 , -CON (R 132 ) (R 133) , -NHCOR 12 , -CH 2 , -OCOR 12 , phenoxy and / or C 1 -C 18 alkyl, C 1 -C 18 alkoxy or halogen C 1 -C 18 substituted by substituted phenoxy, or: C 3 -C 18 alkenyl, C 6 -C 12 cycloalkyl; C 1 -C 4 alkyl and / or -OCOR 12 -substituted C 6 -C 12 cycloalkyl: C 1 -C 4 alkyl which contains one or more -O- in the middle and which is unsubstituted or substituted by OH or O-CO-R 12 3 -C 50 alkyl; Phenyl; Phenyl, -C 1 -C 4 alkyl; -COR 12 or - I 2 R 12, and; R 132 and R 133 are independently C 1 -C 12 alkyl, C 3 -C 12 alkoxyalkyl, C 4 -C 16 dialkylaminoalkyl or C 5 -C 12 together Cycloalkyl; Alkyl, or R 132 and R 133 are each together C 3 -C 6 alkylene, C 3 -C 6 alkylene or oxa-alkylene and azido; X is -NR 8 -, -O-, -NH- (C n H 2n ) -NH- or -O- (C k H 2k ) -NH-; k is a number from 2 to 4; 1 is a number from 0 to 19; m is a number from 2 to 8; n is a number from 0 to 4 and p is a number from 0 to 10; q is a number from 1 to 8; r is a number from 0 to 18 and t is a number from 0, 1 or 2;n n n The compounds of the present invention can be used in organic materials as ultraviolet absorbers.
priorityDate 1994-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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