http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20200108344-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0b009665becdebf38c989424b45622b6 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A43B13-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A43B1-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-025 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F136-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B60C1-0016 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-7006 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B60C1-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F136-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A43B13-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-70 |
filingDate | 2019-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_16c18fd9411fd35d69640657f0740c73 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6b006ca9284c82bf75d4db763857c4f1 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c65af7a4e6107180931ad2d1a572843f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d94f47723b329a029f1460be8b80324d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cd7fe4aedac81a09d41cc69773858b1a |
publicationDate | 2020-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | KR-20200108344-A |
titleOfInvention | Method for producing polyisoprene having mainly alternating CIS-1,4-ALT-3,4 structure in the presence of a catalyst system containing a pyridyl iron complex |
abstract | It mainly relates to a method for producing polyisoprene having an alternating cis -1,4- alt -3,4 structure, the method comprising polymerizing isoprene in the presence of a catalyst system comprising: (a) at least one pyridyl iron complex having the following formula (I): In the above formula (I): -R 1 is selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; -R 2 is selected from linear or branched C 1 -C 10 , preferably C 1 -C 3 , alkyl groups; -X is the same as or different from each other and represents a halogen atom such as chlorine, fluorine, iodine; Or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, -OCOR 3 groups or -OR 3 groups, wherein R 3 is linear or branched C 1 -C 20 , Preferably C 1 -C 15 , selected from an alkyl group; -n is 2 or 3; (b) at least one cocatalyst selected from organo-derivative compounds of aluminum, preferably selected from: (b1) aluminoxane having the following formula (II): In the above formula (II), R 4 , R 5 and R 6 are the same as or different from each other, and represent a hydrogen atom or a halogen atom such as chlorine, fluorine, iodine, or fluorine; Or they are selected from linear or branched C 1 -C 20 alkyl groups, cycloalkyl groups, aryl groups, and the groups are optionally substituted with one or more silicon or germanium atoms; m is an integer ranging from 0 to 1000; (b2) an aluminum compound having the following formula (III): In the above formula (III), R 7 represents a hydrogen atom, or is selected from a linear or branched C 1 -C 20 alkyl group, a cycloalkyl group, an aryl group, an alkylaryl group, an arylalkyl group, and an alkoxy group; R 8 and R 9 are the same as or different from each other, and are selected from a linear or branched C 1 -C 20 alkyl group, a cycloalkyl group, an aryl group, an alkylaryl group, an arylalkyl group; Here, the molar ratio between the aluminum present in the cocatalyst and the iron present in the pyridyl iron complex having the formula (I) is in the range of 5 to 60, preferably 8 to 55. |
priorityDate | 2018-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
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