http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20180123197-A

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publicationDate 2018-11-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20180123197-A
titleOfInvention Copper-Indium-Gallium-Chalcogenide Nanoparticle Precursors for Thin-Film Solar Cells
abstract Nanoparticles containing IUPAC 11 group ions, Group 13 ions and sulfur ions are synthesized by adding a metal salt and an alkanethiol to an organic solvent and heating to promote the reaction. The nanoparticles are formed at a low temperature of about 200 ° C. The nanoparticles may be thermally annealed at a temperature below the reaction temperature for a period of time (typically ~ 40 ° C or lower) to improve the topology and narrow the size distribution. After the reaction is complete, the nanoparticles may be separated by addition of non-solvent and redispersed in an organic solvent such as toluene, chloroform and hexane to form a nanoparticle ink. Additives can be incorporated into the reaction solution to adjust the viscosity of the final ink.
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