http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20170012974-A

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publicationDate 2017-02-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20170012974-A
titleOfInvention Novel method for preparation of polybenzimidazole under mild condition
abstract The present invention relates to a preparation method of polybenzimidazole comprising the following steps of: I) mixing an aromatic tetraamine monomer and a bisulfite adduct of aromatic dialdehyde as reactants for 1-2 hours without adding a solvent; II) adding an organic solvent to the reactants, and conducting condensation polymerization of the resultant product at 150-200C for 15-24 hours to obtain a polymer solution; and III) obtaining polybenzimidazole powder by passing the polymer solution through a series of processes of precipitating in deionized water, cleaning, and drying.
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