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publicationDate 2012-06-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20120063069-A
titleOfInvention Process for producing high purity lithium hydroxide and lithium carbonate from brine
abstract The present invention comprises the steps of precipitating and removing impurities of magnesium, boron and calcium contained in the brine by adding NaOH to the brine; Injecting phosphoric acid or a phosphate compound into the remaining filtrate after the impurities are removed and heating the precipitate to recover lithium contained in the filtrate with lithium phosphate; Dissolving the recovered lithium phosphate in phosphoric acid to prepare an aqueous lithium phosphate solution; Preparing an aqueous lithium hydroxide solution by electrolyzing the prepared lithium phosphate aqueous solution with an electrolysis device in which a positive electrode cell and a negative electrode cell are partitioned by a cation exchange membrane; A method of recovering high purity lithium hydroxide from brine, comprising recovering solid lithium hydroxide by heating the prepared lithium hydroxide aqueous solution; Adding NaOH to brine to precipitate and remove impurities of magnesium, boron and calcium contained in the brine; Injecting phosphoric acid or a phosphate compound into the remaining filtrate after the impurities are removed and heating the precipitate to recover lithium contained in the filtrate with lithium phosphate; Dissolving the recovered lithium phosphate in phosphoric acid to prepare an aqueous lithium phosphate solution; Preparing an aqueous lithium hydroxide solution by electrolyzing the prepared lithium phosphate aqueous solution with an electrolysis device in which a positive electrode cell and a negative electrode cell are partitioned by a cation exchange membrane; Reacting the prepared lithium hydroxide aqueous solution with CO 2 gas or sodium carbonate to precipitate lithium carbonate; It provides a high-purity lithium carbonate recovery method from brine comprising the; filtering the precipitated lithium carbonate to recover lithium carbonate. According to the present invention, impurities can be removed from the brine at a low cost while minimizing the loss of lithium, and the salt-dissolved lithium is precipitated using lithium phosphate having low solubility, thereby eliminating the need for evaporation and concentration of the brine for a long time and eco-friendly. In addition, economically, lithium hydroxide and lithium carbonate can be produced with high purity.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110357055-A
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