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filingDate 2009-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fd3da71d54707f2a1dcb61424ef57ff5
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publicationDate 2011-04-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20110044781-A
titleOfInvention Preparation of Methylenedianiline and Mixtures of Higher Homologs thereof Using Calcined Metal Oxide-Silica Catalyst
abstract The present disclosure discloses amines (eg, methylenedianiline (MDA) with acid catalysts, including, for example, metal oxide-silica catalysts calcined at temperatures above about 500 ° C. to form solid acid silica-metal oxide catalysts. A composition, system, and method for the formation of)). The metal oxide of the solid acid silica-metal oxide catalyst may comprise alumina. The process for preparing the solid acid silica-metal oxide catalyst may include calcining the amorphous alumina-silica material at a temperature of about 500 ° C. or higher and / or under anhydrous and / or inert atmosphere. The rearrangement reaction of the condensation product of aniline with formaldehyde in the presence of a solid acid silica-metal oxide catalyst is more preferred of more MDA and / or MDA than the reaction carried out using the corresponding catalyst calcined at temperatures below 500 ° C. Isomer (s) can be generated.
priorityDate 2008-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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