| abstract |
The present invention is a porous copper-based amide coordination polymer compound of 3D form used as hydrogen storage, adsorbent for toxic substances and catalyst using N, N'-1,4-phenylenedinicotinamide and CuCl 2 as organic ligands, and a method of preparing the same To provide.n n n The porous copper-based amide coordination polymer compound of the 3D form according to the present invention comprises the steps of: stirring 1,4-benzenediamine (benzene-1,4-diamine), nicotinic acid (nicotinic acid) in the presence of a solvent; Adding triphenyl phosphite and heating and stirring; Terminating the heating and cooling at room temperature to form a pale yellow-green N, N '-(1,4-phenylene) dinicotinamide ligand; The N, N'-1,4-phenylenedinicotinamide (N, N '-(1,4-phenylene) dinicotinamide) ligand was dissolved in N, N-dimethylformamide (DMF) and copper was dissolved in methanol ( MeOH), each of which is characterized in that it comprises a step of forming a crystal by self-assembly. |