http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20100067626-A

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publicationDate 2010-06-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20100067626-A
titleOfInvention Process for preparing isocyanate in gas phase
abstract Aromatic isocyanates are prepared by reacting at least one aromatic primary amine with phosgene in the gas phase. The phosgene and the primary aromatic amine are reacted at a temperature higher than the boiling point of the amine in a reactor having a reaction space that is essentially rotationally symmetric about the flow direction. The flow rate, averaged over the cross section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the zone of the reaction space where the conversion of the amine groups to isocyanate groups is 4 to 80%, is 8 m / sec or less. The flow rate, averaged over the cross section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the zone of the reaction space where the conversion of the amine group to the isocyanate group is from 4 to 80%, crosses the cross section at the starting point of this zone. Always lower than the averaged flow rate.
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