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publicationDate 2010-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20100063747-A
titleOfInvention Method for producing lithium ion accumulating and releasing material, lithium ion accumulating and releasing material, electrode structure and power storage device using the material
abstract Provided are methods for producing a material that can electrochemically accumulate or release large amounts of lithium ions. The primary particles of silicon or tin are composed of crystal particles having a diameter of 5 nm to 200 nm having an amorphous surface layer having a thickness of 1 nm to 10 nm, and the amorphous surface layer of the primary particles is composed of at least a metal oxide, The Gibbs free energy when the metal oxide is produced by oxidation of the metal is smaller than the Gibbs free energy when the silicon or tin is oxidized, and the metal oxide is thermodynamically more stable than silicon oxide or tin oxide. Electrode material for negative electrodes of electrical storage devices which can accumulate and discharge | release lithium ion chemically. (I) a step of reacting silicon or tin with a metal oxide, (ii) a step of reacting a silicon oxide or tin oxide with a metal, or (iii) a step of reacting a silicon compound or a tin compound with a metal compound. The manufacturing method of the electrode material for negative electrodes of the electrical storage device which can accumulate and discharge | release lithium ion.
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