http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20090112862-A

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publicationDate 2009-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20090112862-A
titleOfInvention Separation Recovery Method of Uranium for Spent Fuel Using High Alkaline Carbonate Solution System and Its Apparatus
abstract The present invention relates to a method for recovering and recovering uranium from spent fuel using a high alkaline carbonate solution system. The object of the present invention is to select only uranium from spent fuel, while providing environmental protection to minimize nuclear proliferation resistance and waste generation. To separate and recover.n n n The present invention provides an oxidation power between the uranium oxide (UO 2 ) redox equilibrium voltage and the redox equilibrium voltage of plutonium oxide (PuO 2 ), neptunium oxide (NpO 2 ) and americium oxide (AmO 2 ). A uranium dissolution leaching step of dissolving only uranium (U) in the form of uranyl oxo carbonate complex ions by hydrogen peroxide (H 2 O 2 ), which is an oxidizing agent having a; Cesium-technetium precipitation step of precipitating and separating cesium (Cs) and technetium (Tc) by an organic precipitant; The uranium precipitate containing the uranium solution is adjusted to pH 2-4 by acid in the uranium precipitation tank to precipitate uranium in the form of UO 4 oxide and absorbs the carbon dioxide gas generated at the same time so that it can be recovered and recycled to the carbonate. Carbonate recovery step; And an acid-alkali recovery step for recovering the acid and alkali solution used in the uranium precipitation-carbonate recovery step while removing the impurity metal ions remaining in the solution depleted of uranium and carbonate.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2018221811-A1
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