http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20050007603-A

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filingDate 2003-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_56dbaf45400e4688805e38d614844ac5
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publicationDate 2005-01-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20050007603-A
titleOfInvention Two-stage method for producing butane diol with intermediate separation of succinic anhydride
abstract The present invention relates to a process for two-step catalytic hydrogenation of C 4 -dicarboxylic acid and / or derivatives thereof in the gas phase to produce optionally alkyl-substituted 1,4-butanediol. The process comprises (a) introducing a gaseous stream of C 4 -dicarboxylic acid or derivative thereof into the first reactor at 200 to 300 ° C. and 2 to 60 bar and catalytic gas phase hydrogenation, optionally alkyl-substituted γ-butyrol Producing a product comprising lactone, (b) separating succinic anhydride from the product obtained in step (a), preferably achieving a residual amount of about 0.3 to 0.2% by weight, and (c) obtaining in step (b) The product stream is introduced into a second reactor at a temperature of 150-240 ° C. and a pressure of 15-100 bar to catalyze gas phase hydrogenation to obtain optionally alkyl-substituted 1,4-butanediol, (d) the desired product as an intermediate, Separating from the by-product and any unconverted reactants, and (e) optionally recycling the unconverted intermediate product to one or both of the hydrogenation steps, wherein ≦ 95% by weight, preferably 5-9 A catalyst comprising 5% by weight, in particular 10-80% by weight of CuO and ≧ 5% by weight, preferably 5 to 95% by weight, in particular 20 to 90% by weight of oxidizing support, is used in each hydrogenation step and the second The pressure of the reactor is higher than the first reactor.
priorityDate 2002-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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