http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20020075408-A

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filingDate 2000-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2002-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20020075408-A
titleOfInvention Continuous Process for Producing Bis(3-Hydroxypropyl) Terephthalate
abstract The present invention relates to a process for the continuous preparation of at least one of bis (3-hydroxypropyl) terephthalate and low molecular weight oligomers of 1,3-propanediol with terephthalic acid. According to the process of the invention, the lower dialkyl esters of preheated (about 150 to about 200 ° C.) 1,3-propanediol and preheated (about 150 to about 220 ° C.) terephthalic acid are from about 1.2: 1 to about 2.3: 1 Of the mixture is fed to a transesterification vessel to effect continuous transesterification of the mixture. The liquid reaction mixture is continuously heated and mixed at a temperature of about 215 to about 250 ° C. and a pressure of about 800 to about 1,000 mmHg. The gaseous reaction product is continuously separated from the liquid reaction mixture, and the stream of liquid reaction product containing bis (3-hydroxypropyl) terephthalate and low molecular weight oligomers of 1,3-propanediol with terephthalic acid is transesterified. It is continuously removed from the base of.
priorityDate 2000-02-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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