http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20010060160-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_f4a7711656877c108fcffc1b2b52cfc4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_b5b9f9cd8f41ddd9b8e5bc26a4d68518 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C229-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D207-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0046 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 |
filingDate | 2000-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_906ac60128e327cc2f1688a44fd11ed3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dadf6de1b4ba334c163d483e1aab0717 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b5d862873f8324075c3df1a457e3828f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3828314e832e5a77adf222b2c0c9a243 |
publicationDate | 2001-07-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | KR-20010060160-A |
titleOfInvention | Method for preparing chiral ester |
abstract | The present invention provides a process for preparing chiral esters from racemic alkenyl esters. The preparation method includes a lipase for selectively acylating an alkenyl ester, a ruthenium complex of Formulas 1 to 2 which promotes a reduction reaction and a racemization reaction of the alkenyl ester, and one enantiomer of the racemic alkenyl ester. And a reducing agent for supplying a hydride to the ruthenium complex. According to the present invention, chiral esters having excellent optical purity characteristics can be obtained in a high synthetic yield through a one-step reaction from alkenyl esters having various structures.n n n n n n n n n n In the above formula, Y 1 , Y 2 , Y 3 , Y 4 , Y 5 , Y 6 , Y 7 , Y 8 , Y 9 , Y 10 , Y 11 , Y 12 represent a single bond irrespective of each other, Hydrogen or an alkyl group having 1 to 5 carbon atoms and X is Br, Cl or I, Q is H, Br, Cl or I,n n n n n n n n n n In said formula, Ph represents a phenyl group. |
priorityDate | 1999-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 81.