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publicationDate 2000-04-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20000020026-A
titleOfInvention High refractive index wear resistant coating composition with excellent impact resistance
abstract (A) (A) 0-75% by weight of aqueous or alcoholic colloidal silica of pH 2.5-4, 0.1-50% by weight of hydrolyzate or partial condensate of organosilane of formula (1) relative to the total solids content of the base resin component And a base resin comprising 10-30% by weight of the hydrolyzate or partial condensate of the organosilane of formula (2) relative to the total composition content comprising a solvent, (b) 1-100 parts by weight of a high refractive oxide of formula (3) A coating composition comprising 0.1-10 parts by weight of an aluminum alkoxide of Formula 4, a hydrolyzate or partial condensate thereof, and (D) 10-50 parts by weight of a ketone or diketone of C 1 -C 12 , and (B) the coating composition; The siloxane-based high refractive index wear-resistant coating composition including epoxy or urethane resin, which is a primer for enhancing adhesion between substrates, has excellent storage stability, curability, abrasion resistance, and solvent resistance, and has a primer layer. At the same time it shows excellent adhesion with exhibits excellent impact resistance and shows a high refractive index and high hardness.n n n [Formula 1]n n n R 1 a Si (OR 2 ) 4-a n n n [Formula 2]n n n R 3 b Si (OR 4 ) 4-b n n n [Formula 3]n n n M 1 X M 2 Y O Z n n n [Formula 4]n n n Al (OR 8 ) 3 n n n Wherein R 1 and R 2 are each independently selected from the group consisting of C 1 -C 6 alkyl, alkenyl, halogenated alkyl, allyl and aromatic groups, a is an integer from 0 to 3, and R 3 is (R 5 is an alkylene radical of C 1 -C 4 , R 6 is a hydrogen atom or an alkyl radical of C 1 -C 4 ) or Is an (R 7 is a hydrogen atom, an alkyl radical of C 1 -C 4 alkylene radical or a C 1 -C 4), R 4 is an alkyl group of C 1 -C 6, b is an integer from 0 to 3, M 1 and M 2 are each independently selected from the group consisting of titanium, antimony, zirconium and tin, X, Y and Z are integers of 0 to 5, and R 8 is an alkyl group of C 1 -C 6 .
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