http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-102107272-B1
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D493-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0211 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J27-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0215 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0257 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D493-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J27-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 |
filingDate | 2014-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2020-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2020-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | KR-102107272-B1 |
titleOfInvention | Enhanced regio-selectivity in glycol acylation |
abstract | Methods of acid-catalyzed acylation of isohexides have been described. The method involves the reaction of isohexide and excess carboxylic acid in the presence of a Lewis acid or Bronsted acid catalyst. One or more Lewis acids and / or Bronsted acids can achieve high conversion rates of isohexide to the corresponding mono and diesters with much higher regioselectivity of exo -OH than the endo -OH of isohexide in the product. have. Certain catalytic acid species include zirconium chloride (ZrCl 4 ) and phosphonic acid (H 3 PO 3 ), which exhibit ratios of exo : endo reactivity of about 5: 1 and 4: 1, respectively. |
priorityDate | 2013-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 70.