http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-101811967-B1

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filingDate 2013-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2018-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-101811967-B1
titleOfInvention An Additive for Reducing Voids after Annealing of Copper Plating with TSV
abstract The present invention provides an additive for void reduction after annealing of copper plating using TSV. Wherein the additive comprises 0.05 wt% to 1 wt% of at least one quaternized polyethyleneimine and derivatives thereof having different molecular weights, and 1 wt% to 10 wt% of polyethylene glycol having an average molecular weight of 200-20000 . The additive is used in combination with an electroplating solution of a copper methyl sulfonate system. The electroplating solution of the copper methyl sulfonate system contains 1-5 ml / L of the additive in volume ratio. The electroplating solution of the copper methyl sulfonate system comprises 50-110 g / L of copper ion, 5-50 g / L of methane sulfonic acid and 20-80 mg / L of chloride ion in a mass ratio by volume. The electroplating solution also contains 0.5-5 ml / L of accelerator, 5-20 mL of inhibitor and 5-10 ml / L of leveling agent in volume ratio. The porosity reducing additive after annealing of copper plating using the TSV of the present invention can solve the problem of micro-voids between crystal grain boundaries after high temperature annealing of copper plating.
priorityDate 2013-08-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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