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filingDate 2012-04-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2014-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-101365138-B1
titleOfInvention Polythiophene star polymer copolymer which can be self-doped by external stimulation, its preparation method, conductive thin film using same and its manufacturing method
abstract The present invention comprises the steps of forming a polythiophene macro initiator having a functional group capable of living radical polymerization at the terminal of the polythiophene or derivatives thereof; Forming a polymer macroinitiator through living radical polymerization to provide one or more dopants selected from the group consisting of sulfone groups, carboxyl groups and phosphoric acid groups by external stimulation; And polymerizing a polythiophene star polymer copolymer by adding the polymer macroinitiator and at least one divinyl monomer to the polythiophene macro initiator. The polythiophene star polymer copolymer may include a microgel core including a homopolymer of divinyl monomers or a copolymer of two or more divinyl monomers; And a heteroarm chain comprising a polythiophene or derivative thereof bound to the core, and a polymer providing one or more dopants selected from the group consisting of sulfone groups, carboxyl groups and phosphoric acid groups by external stimulation. It provides a method of producing a polythiophene star polymer copolymer capable of self-doping by external stimulation. The polythiophene star polymer copolymer capable of self-doping by an external stimulus according to the present invention can be used as a material of a conductive thin film by stably increasing conductivity as a magnetic doping material.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9260572-B2
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