abstract |
In order to remove the sulfur compound in the gas by supplying a hydrocarbon-containing gas to the desulfurization layer, a desulfurization layer comprising a desulfurization agent A containing zeolite and a desulfurization agent B composed of at least one selected from a metal element, a metal oxide and a metal component supported oxide, A method for removing sulfur compounds in a hydrocarbon-containing gas to be used, and a method for producing hydrogen for a fuel cell, in which a hydrocarbon-containing gas desulfurized by this method is contacted with a partial oxidation reforming catalyst, a magnetothermal reforming catalyst, or a steam reforming catalyst. According to the method of the present invention, by using two kinds of desulfurization agents having different desulfurization performances in combination, and by using a source gas having a low carbonyl sulfide concentration, all sulfur compounds in the hydrocarbon-containing gas are efficiently removed even at room temperature to low concentrations. can do. In addition, by reforming the desulfurization hydrocarbon-containing gas obtained by the above method, hydrogen for fuel cells can be produced economically advantageously. |