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filingDate 1997-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2000-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-100261509-B1
titleOfInvention Lithium composite oxides, producing method thereof, and lithium secondary battery having the same as active material of cathode
abstract The aqueous solution of cobalt salt and nickel salt is added to the aqueous solution of ammonia as a complex and an alkaline solution as a pH regulator and co-precipitated for a predetermined time to form a nickel-cobalt composite hydroxide in which the aggregates of acicular primary particles form spherical secondary particles. Lithium prepared by the method comprising the steps of adding lithium hydroxide to the composite hydroxide, the first heat treatment at 280-420 ℃, and the second heat treatment at 650-700 ℃ the result obtained by the first heat treatment The composite oxide (LiNi (1-xy) Co x M y O 2 (M = Al, Ca, Mg and B is at least one metal atom selected from x, 0.1 is 0.3 to 0.3, y is 0 to 0.1)) The aggregate of a rectangular primary particle forms a spherical secondary particle, and the tap density is high. When the lithium composite oxide is used as a positive electrode active material, a high capacity lithium ion secondary battery can be obtained.
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