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filingDate 1993-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1999-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_98a0a93dac19f19b07e05b01d30dcb15
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_48b250283aa1614e00290b280aff7d9c
publicationDate 1999-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-100222277-B1
titleOfInvention Method for preparing catalyst for methacrylic acid production
abstract The present invention is a method for producing a catalyst represented by the following formula used to produce methacrylic acid by gas phase catalytic oxidation of methacrolein with molecular oxygen, Pa, Mob, Vc, Ged, Xe, Tf, Zg, Oh Wherein P, Mo, V, Ge and O represent phosphorus, molybdenum, vanadium, germanium and oxygen, respectively, and X is at least selected from the group consisting of arsenic, antimony, bismuth, zirconium, tellurium, silver and boron Represents one element, Y represents at least one element selected from the group consisting of iron, copper, zinc, chromium, magnesium, tantalum, manganese, barium, gallium, cerium and lanthanum, and Z represents potassium, rubidium , At least one element selected from the group consisting of cesium and thallium, a, b, c, d, e, f and g represent the atomic ratio of each element, b When 12, a 0.5 3, c 0.01 3, d 0.01 3, e 0 3, f 0 3, g 0.01 3, h is the number of oxygen atoms required to satisfy the valences of the respective components, germanium dioxide is used as the germanium material, and at least a part of the germanium dioxide is dissolved in an aqueous solution of the hydroxide of the element represented by Z in the above general formula. . The catalyst prepared by the present invention can significantly increase the activity in the oxidation reaction of methacrolein to increase the yield of catacrylic acid.
priorityDate 1993-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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