http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-WO2006001387-A1
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-70 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0237 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0235 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-006 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D471-08 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D451-14 |
| filingDate | 2005-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2008-04-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | JP-WO2006001387-A1 |
| titleOfInvention | Alcohol oxidation catalyst and synthesis method thereof |
| abstract | The present invention proposes an organic oxidation catalyst for alcohols which is excellent in environmental harmony and enables more efficient oxidation, and a synthesis method thereof. 1-Alkyl-2-azaadamantane-N-oxyl synthesized with a nitroxyl group on the adamantane skeleton, synthesized from a bicyclo isomer obtained by Grob-type ring cleavage reaction of 1,3-adamantanediol, as an alcohol As an oxidation catalyst. By having a nitroxyl group on the adamantane skeleton, hydrogen at the α-position is stabilized by the Bredt rule, and the stability of the oxoammonium group generated by oxidation of this is guaranteed, and steric hindrance compared to TEMPO, which is a conventional oxidation catalyst Decreases and a wide reaction field can be secured. For this reason, the secondary alcohol having a sterically complicated structure, which is difficult to oxidize with TEMPO, can be oxidized with high efficiency, as well as the oxidation of the primary alcohol. |
| priorityDate | 2004-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 106.