http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S6429372-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_dfd617dc43a4c986d2dd81e4cb39d9dd http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_ca8b8054ec556557dc4a22354a873d77 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-55 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D311-94 |
filingDate | 1987-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_12b5fbd03d4cd1a2ad4fb3874405b462 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4224e225def950f8b4e4c6273589f2ec |
publicationDate | 1989-01-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S6429372-A |
titleOfInvention | Brassinolide analogous compound |
abstract | NEW MATERIAL:A compound expressed by formula I (X and Y are H, OH, CH3 or CH2OH; Z is H, OH, lower alkyl; X and Y together may form methylene or -CH2O-, except when X is CH3 and Y and Z are H). EXAMPLE:(22R,23R,24R)-2alpha,3alpha,22,23,28-Pentahydroxy-beta-homo-7- oxa-5alpha-ergostan-6- one [= 28-hydroxybrassinolide (X is CH3; Y is H; Z is OH in formula I)]. USE:A plant growth regulator capable of exhibiting excellent physiological action in rice plant lamina bending tests and wheat lamina extending tests utilized as biological tests of plant hormone. PREPARATION:A castasterone derivative expressed by formula II (R is OH- protecting group) is subjected to the Baeyer-Villiger oxidation to provide a lactone ring in a solvent, such as CH2Cl2, using H2O2 and trichloroperacetic acid and the resultant product is subsequently refluxed in KOH-MeOH while being heated to remove all the OH-protecting groups and afford the aimed compound expressed by formula I. |
priorityDate | 1987-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 35.