http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S6377885-A

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filingDate 1986-09-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a4637953de4fc8fd2a509946b9fc404c
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publicationDate 1988-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6377885-A
titleOfInvention Silylated carbacyclins and production of isocarbacyclins utilizing said silylated carbacyclins
abstract NEW MATERIAL:A compound (enantiomer) expressed by formula I [R 1 WR 3 are 1W7C hydrocarbon: R 4 is H, methyl or vinyl; R 5 is 3W9C alkyl, alkenyl, (substituted) phenyl which may contain oxygen atom, etc.; R 6 is H or formula II (R 61 is H, 1W8C hydrocarbon ester, etc., m is an integer of 0W6); R 71 and R 81 are trihydrocarbonsilyl, etc.; n is 0 or 1; the wavy line indicates that steric configuration of double bond is E, Z, etc.]. n USE: An intermediate for producing antithrombotic agents. n PREPARATION: For example, 9-deoxy-9-formyl-5,6-dehydroPGE 2 s expressed by formula III (R 6a is the same kind as that of R 6 ) are reacted with a lithium compound expressed by formula IV, then treated with carbon disulfide, reacted with a halogen compound expressed by the formula R 9 X (X is halogen; R 9 is methyl or ethyl) and subsequently reacted with tri-n-butyltin hydride in the presence of tert-butyl peroxide to afford the aimed compound expressed by formula I. n COPYRIGHT: (C)1988,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-2599695-A1
priorityDate 1986-09-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 33.