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filingDate 1986-09-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_eed1cb2ec691d41517f2532d786c0383
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publicationDate 1988-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6377836-A
titleOfInvention Production of acenaphthenone
abstract PURPOSE: To obtain the titled substance, by oxidizing acenaphthene with a gas containing molecular oxygen in the presence of a transition metal-bromine catalyst at a temperature below a specific level in a mixed solvent consisting of a lower fatty acid and an inert organic solvent having high solubility of acenaphthene. n CONSTITUTION: Acenaphthenone is produced by carrying out the oxidization of acenaphthene with O 2 -containing gas in the presence of a transition metal- bromine catalyst at ≤60°C (preferably 20W50°C) using a 2W10C lower fatty acid as a solvent. To improve the solubility of acenaphthene in the reaction system, it is preferable to add an inert organic solvent having high solubility of acenaphthene, preferably an aromatic hydrocarbon free from alkyl side chain, e.g. benzene, halogenated aromatic hydrocarbon, etc., to the reaction system. There is not production of by-product gas (exhaust gas) because of low- temperature oxidization. The dissipation of highly volatile component can be prevented and the objective compound can by produced in high selectivity. n COPYRIGHT: (C)1988,JPO&Japio
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