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filingDate 1987-04-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6bfdeedc0c9f1818a4d7c070a040b178
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publicationDate 1988-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S63255273-A
titleOfInvention Purification of glycidyl acrylate or glycidyl methacrylate
abstract PURPOSE: To obtain the titled high-purity compound having low chlorine content, substantially containing no epichlorohydrin of a raw material, by treating the titled crude compound with a specific heteropolyacid to deactivate a quaternary ammonium salt catalyst and separating by distillation. n CONSTITUTION: Crude glycidyl acrylate (or methacrylate) obtained by reacting an alkali metallic salt of acrylic acid (or methacrylic acid) with epichlorohydrin in the presence of a quaternary ammonium salt catalyst is treated with at least one of a heteropolyacid shown by the formula (X is P or Si; Y is W or Mo; Z is H, Li, Na or K; m is 3 when X is P and m is 4 when X is Si; n is 0W30 positive integer) and an alkali metallic salt thereof to deactivate the catalyst and separated by distillation to give glycidyl acrylate (or methacrylate) having ≤0.01 epichlorohydrin content useful as a raw material for coating compounds and resists. n COPYRIGHT: (C)1988,JPO&Japio
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