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filingDate 1987-10-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_16a6cd115099b21c181192e06b8324b0
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publicationDate 1988-09-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S63225330-A
titleOfInvention Production of alpha,beta-unsaturated ketone
abstract PURPOSE:To economically produce the titled compound useful as a raw material for organic syntheses and solvent, by condensing the same ketones and different ketones through dehydration in a liquid phase by the use of an oxide or hydroxide of tin or iron as a catalyst. CONSTITUTION:A ketone shown by formula I (R<1> is H or alkyl; R<2> is alkyl) is condensed with a ketone shown by formula II (R<3> is H or alkyl; R<4> is alkyl) through dehydration in the presence of a highly active ketone condensation catalyst comprising an oxide or hydroxide of tin or iron (e.g. stannic acid, ferric hydroxide, stannic oxide and alpha-ferric oxide) in a liquid phase to give an alpha,beta-unsaturated ketone (e.g. mesityl oxide). Oxides in the catalyst may be hydrous oxides.
priorityDate 1986-10-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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